2-Bromopropane

2-Bromopropane, also known as isopropyl bromide and 2-propyl bromide, is the halogenated hydrocarbon with the formula CH3CHBrCH3. It is a colorless liquid. It is used for introducing the isopropyl functional group in organic synthesis. 2-Bromopropane is prepared by heating isopropanol with hydrobromic acid.

2-Bromopropane
Names
Preferred IUPAC name
2-Bromopropane
Other names
Isopropyl bromide
Identifiers
3D model (JSmol)
741852
ChEMBL
ChemSpider
ECHA InfoCard 100.000.778
EC Number
  • 200-855-1
MeSH 2-bromopropane
PubChem CID
RTECS number
  • TX4111000
UNII
UN number 2344
  • InChI=1S/C3H7Br/c1-3(2)4/h3H,1-2H3 Y
    Key: NAMYKGVDVNBCFQ-UHFFFAOYSA-N Y
SMILES
  • CC(C)Br
Properties
C3H7Br
Molar mass 122.993 g·mol−1
Appearance Colorless liquid
Density 1.31 g mL−1
Melting point −89.0 °C; −128.1 °F; 184.2 K
Boiling point 59 to 61 °C; 138 to 142 °F; 332 to 334 K
3.2 g L−1 (at 20 °C)
log P 2.136
Vapor pressure 32 kPa (at 20 °C)
1.0 μmol Pa−1 mol−1
Refractive index (nD)
1.4251
Viscosity 0.4894 mPa s (at 20 °C)
Thermochemistry
135.6 J K mol−1
Std enthalpy of
formation fH298)
−129 kJ mol−1
−2.0537–−2.0501 MJ mol−1
Hazards
GHS labelling:
Danger
H225, H360, H373
P210, P308+P313
NFPA 704 (fire diamond)
2
3
0
Flash point 19 °C (66 °F; 292 K)
Related compounds
Related alkanes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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