1,8-Bis(dimethylamino)naphthalene

1,8-Bis(dimethylamino)naphthalene is an organic compound with the formula C10H6(NMe2)2 (Me = methyl). It is classified as a peri-naphthalene, i.e. a 1,8-disubstituted derivative of naphthalene. Owing to its unusual structure, it exhibits exceptional basicity. It is often referred by the trade name Proton Sponge, a trademark of Sigma-Aldrich.

1,8-Bis(dimethylamino)naphthalene
Names
Preferred IUPAC name
N1,N1,N8,N8-Tetramethylnaphthalene-1,8-diamine
Other names
N,N,N,N-Tetramethylnaphthalene-1,8-diamine
Proton Sponge
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.039.986
PubChem CID
UNII
  • InChI=1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3 Y
    Key: GJFNRSDCSTVPCJ-UHFFFAOYSA-N Y
  • InChI=1/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
    Key: GJFNRSDCSTVPCJ-UHFFFAOYAM
SMILES
  • CN(C)C1=CC=CC2=C1C(=CC=C2)N(C)C
  • c1(cccc2cccc(N(C)C)c12)N(C)C
Properties
C14H18N2
Molar mass 214.312 g·mol−1
Appearance White crystalline powder
Melting point 47.8 °C (118.0 °F; 320.9 K)
Acidity (pKa) 12.1 (in water)

18.62 (in acetonitrile)
(acidity of the conjugate acid C14H18N2H+)

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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