1,2-Diaminopropane

1,2-Diaminopropane (propane-1,2-diamine) is organic compound with the formula CH3CH(NH2)CH2NH2. A colorless liquid, it is the simplest chiral diamine. It is used as a bidentate ligand in coordination chemistry.

1,2-Diaminopropane
Names
Preferred IUPAC name
Propane-1,2-diamine
Other names
1,2-Propanediamine
Identifiers
3D model (JSmol)
605274
ChEBI
ChemSpider
ECHA InfoCard 100.001.051
EC Number
  • 201-155-9
25709
MeSH 1,2-diaminopropane
PubChem CID
RTECS number
  • TX6650000
UNII
UN number 2258
  • InChI=1S/C3H10N2/c1-3(5)2-4/h3H,2,4-5H2,1H3 Y
    Key: dAOHJOMMDDJHIJH-UHFFFAOYSA-N N
SMILES
  • CC(N)CN
Properties
C3H10N2
Molar mass 74.127 g·mol−1
Appearance Colourless liquid
Odor Fishy, ammoniacal
Density 870 mg mL−1
Melting point −37.1 °C; −34.9 °F; 236.0 K
Boiling point 119.6 °C; 247.2 °F; 392.7 K
Vapor pressure 1.9 kPa (at 20 °C)
Magnetic susceptibility (χ)
-58.1·10−6 cm3/mol
Refractive index (nD)
1.446
Thermochemistry
205.64 J K−1 mol−1
Std molar
entropy (S298)
247.27 J K−1 mol−1
Std enthalpy of
formation fH298)
−98.2–−97.4 kJ mol−1
−2.5122–−2.5116 MJ mol−1
Hazards
GHS labelling:
Danger
H226, H302, H312, H314
P280, P305+P351+P338, P310
Flash point 34 °C (93 °F; 307 K)
360 °C (680 °F; 633 K)
Explosive limits 1.9–11.1%
Lethal dose or concentration (LD, LC):
LD50 (median dose)
  • 434 mg kg−1 (dermal, rabbit)
  • 2.23 g kg−1 (oral, rat)
Related compounds
Related alkanamines
Related compounds
2-Methyl-2-nitrosopropane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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