1,1,2-Trichloroethane
1,1,2-Trichloroethane, or 1,1,2-TCA, is an organochloride solvent with the molecular formula C2H3Cl3 and the structural formula CH2Cl—CHCl2. It is a colourless, sweet-smelling liquid that does not dissolve in water, but is soluble in most organic solvents. It is an isomer of 1,1,1-trichloroethane, and a byproduct of its manufacture.
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Names | |||
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Preferred IUPAC name
1,1,2-Trichloroethane | |||
Other names
1,1,2-TCA vinyl trichloride beta-trichloroethane, symmetrical Trichloroethane, monochlorethylen chloride (archaic) | |||
Identifiers | |||
3D model (JSmol) |
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ChEBI | |||
ChEMBL | |||
ChemSpider | |||
ECHA InfoCard | 100.001.061 | ||
KEGG | |||
PubChem CID |
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UNII | |||
CompTox Dashboard (EPA) |
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SMILES
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Properties | |||
C2H3Cl3 | |||
Molar mass | 133.40 g/mol | ||
Appearance | colorless liquid | ||
Odor | sweet, chloroform-like (in high concentrations) | ||
Density | 1.435 g/cm3 | ||
Melting point | −37 °C (−35 °F; 236 K) | ||
Boiling point | 110 to 115 °C (230 to 239 °F; 383 to 388 K) | ||
0.4% (20°C) | |||
Vapor pressure | 19 mmHg (20°C) | ||
Hazards | |||
NFPA 704 (fire diamond) |
3
1 | ||
Explosive limits | 6–15.5% | ||
Lethal dose or concentration (LD, LC): | |||
LD50 (median dose) |
1200 mg/kg (rat, orally) | ||
LCLo (lowest published) |
13,100 mg/m3 (cat, 4.5 hr) 2000 ppm (rat, 4 hr) | ||
NIOSH (US health exposure limits): | |||
PEL (Permissible) |
TWA 10 ppm (45 mg/m3) [skin] | ||
REL (Recommended) |
Ca TWA 10 ppm (45 mg/m3) [skin] | ||
IDLH (Immediate danger) |
Ca [100 ppm] | ||
Related compounds | |||
Related compounds |
1,1,1-Trichloroethane; Trichloroethylene | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
It is used as a solvent and as an intermediate in the synthesis of 1,1-dichloroethene.
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